Cobalt carbene ion: Reactions of Co+ with C2H4, cyclo‐C3H6, and cyclo‐C2H4O
نویسندگان
چکیده
منابع مشابه
Synthesis and Reactions with CO and C2H4 of Cobalt(I) Complexes Containing Trimethylphosphine and Chelating o-Diphenylphosphanyl- phenolate Ligands
In tetracoordinate cobalt(I) halide compounds CoX(Ph2P OH)(PMe3)2 (X = Cl, Br) o-phosphanylphenols Ph2P OH are coordinated as phosphane ligands. In the presence of base chelating anions Ph2P O give rise to pentacoordinate complexes Co(Ph2 P O)(PMe3)3. Molecular structures are presented for both types of compounds. The five-membered chelate ring in Co(Ph2P O)(PMe3)3 is resistant to protonation, ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1981
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.441453